A key definition (key_definition) in a CREATE TABLE statement or an ALTER TABLE statement defines the key of a base table. The key definition is introduced by the keywords PRIMARY KEY.
SQL Tutorial, Primary Key
The column name (column_name) must identify a column in the base table. The specified column names are key columns in the table.
A key column must not identify a column of the data type LOB and is always a NOT NULL column. The database system ensures that no key column has a NULL value and that no two rows of the table have the same values in all key columns.